Uncertain Henry's law constants compromise equilibrium partitioning calculations of atmospheric oxidation products

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Lattice Calculations of Decay Constants

Lattice attempts to compute the leptonic decay constants of heavy-light pseu-doscalar mesons are described. I give a short historical overview of such attempts and then discuss some current calculations. I focus on three of the most important sources of systematic error: the extrapolation to the continuum, the chiral extrapolation in light quark mass, and the eeects of quenching. I brieey discu...

متن کامل

Partitioning Uncertain Workflows

It is common practice to partition complex workflows into separate channels in order to speed up their completion times. When this is done within a distributed environment, unavoidable fluctuations make individual realizations depart from the expected average gains. We present a method for breaking any complex workflow into several workloads in such a way that once their outputs are joined, the...

متن کامل

Evaluation of equilibrium constants by affinity chromatography.

Theoretical expressions are derived for affinity chromatography of systems comprising an acceptor A with one binding site for attachment to a functional group X on the column matrix and one site for interaction with a small ligand B that specifically affects its elution. From a general relationship covering all possible interactions between A, B and X simpler expressions are derived for affinit...

متن کامل

Determination of Equilibrium Constants using NMR Spectrscopy

In this laboratory exercise we will measure a chemical equilibrium constant using key proton signals in a Nuclear Magnetic Resonance (NMR) spectrum. Those doing the “traditional” P Chem experiments will examine a keto-enol tautomerism, while those doing the “biophysical” experiments will look at the cis-trans equilibrium for a peptide bond. In each case, the relative concentration of the equili...

متن کامل

Determination of Equilibrium Constants using NMR Spectrscopy

In this laboratory exercise we will measure the Equilibrium Constant Kc for the keto-enol tautomerism of two -diketones and two -diketoesters. This will be accomplished by measuring the signal strength of key protons in the Nuclear Magnetic Resonance (NMR) spectrum of the equilibrium system. The influence of the solvent on the equilibrium position will be examined by considering the measured ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Atmospheric Chemistry and Physics

سال: 2017

ISSN: 1680-7324

DOI: 10.5194/acp-17-7529-2017